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Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds
Vladimir Ya. Lee
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Description for Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds
Hardcover. * First book on the emerging area of the low-coordinate compounds of the heavier group 14 elements silicon, germanium, tin and lead * Written by leading experts in the field: In 2006 Professor Sekiguchi received the Kipping Award, the most important prize in the field of silicon chemistry. Num Pages: 448 pages, Illustrations. BIC Classification: PNND. Category: (P) Professional & Vocational. Dimension: 248 x 172 x 30. Weight in Grams: 880.
Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents.
Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents.
Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species ... Read more
- Si-, Ge-, Sn and Pb-centered cations, radicals and anions
- heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes
- heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes
- heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers
- heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes
- heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16]
- cyclic compounds (three-, four-, five-, and six-membered rings)
- heavy analogues of 1,3-dienes, allenes and other cumulenes
- heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity
Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry
Show LessProduct Details
Format
Hardback
Publication date
2010
Publisher
John Wiley & Sons Inc United Kingdom
Number of pages
448
Condition
New
Number of Pages
448
Place of Publication
New York, United States
ISBN
9780470725436
SKU
V9780470725436
Shipping Time
Usually ships in 7 to 11 working days
Ref
99-50
About Vladimir Ya. Lee
Vladimir Ya. Lee Assistant Professor, Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Japan Vladimir Ya. Lee has worked at the Korea Institute of Science and Technology (Korea), at the Université Paul Sabatier (France), and, since 1998, at the University of Tsukuba (Japan). His research interests lie in the field of highly reactive ... Read more
Reviews for Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds
“In effect, the body of work described constitutes one of the cornerstones of modern main group chemistry and this account provides a highly useful reference source for the specialist as well as a non-intimidating guide for the beginner.” (Applied Organometallic Chemistry, 6 March 2015)